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with coarse grain sizes present great chal- and Melts: Properties and Structure: San Diego,
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must be taken both when choosing ran- Donovan, J.J., 2013, EPMA quantitative Nutman, A.P., Mojzsis, S.J., and Friend, C.R.L.,
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when interpreting data from instruments samples: Lunar and Planetary Institute, 44th sediments in West Greenland and their
with different sampling volumes (Fig. 6). Lunar and Planetary Science Conference, significance for the early Archaean Earth:
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ACKNOWLEDGMENTS examples using THERMOCALC: Journal of
Dyar, M.D., McCanta, M.C., Breves, E., Carey, Metamorphic Geology, v. 16, p. 577–588,
We acknowledge funding from NSF grants C.J., and Lanzirotti, A., 2016, Accurate doi:10.1111/j.1525-1314.1998.00157.x.
EAR-1219850 (MCM) and EAR-1219761 (MDD). predictions of iron redox state in silicate glasses: Valley, J.W., Reinhard, D.A., Cavosie, A.J.,
Reviews from two anonymous reviewers were A multivariate approach using X-ray absorption Ushikubo, T., Lawrence, D.F., Larson, D.J.,
thorough and strengthened this paper. spectroscopy: American Mineralogist, v. 101, Kelly, T.F., Snoeyenbos, D.R., and Strickland,
p. 744–747. A., 2015, Nano- and micro-geochronology in
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